Infrared- and Raman-Active Phonons of Magnetite, Maghemite, and Hematite:  A Computer Simulation and Spectroscopic Study 论文

2005The Journal of Physical Chemistry B引用 434
Iron oxide chemistry and applicationsMineralogy and Gemology StudiesGeochemistry and Geologic Mapping

详细信息

发表期刊/会议
The Journal of Physical Chemistry B
发表日期
2005-02-25
发表年份
2005

关键词

Iron oxide chemistry and applicationsMineralogy and Gemology StudiesGeochemistry and Geologic Mapping

摘要

Magnetite, maghemite, and hematite have been the subject of numerous studies using vibration spectroscopy to determine their infrared- and Raman-active phonons. However, no complete and unambiguous set of experimentally observed optically active phonons has yet been reported for these iron oxides. The use of atomistic simulation methods with a transferable Buckingham potential provides new data for the phonon densities of states of magnetite and the two associated phases, hematite and maghemite.

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