Penglai Zircon Megacrysts: A Potential New Working Reference Material for Microbeam Determination of Hf–O Isotopes and U–Pb Age 论文

摘要

We introduce a potential new working reference material – natural zircon megacrysts from an Early Pliocene alkaline basalt (from Penglai, northern Hainan Island, southern China) – for the microbeam determination of O and Hf isotopes, and U–Pb age dating. The Penglai zircon megacrysts were found to be fairly homogeneous in Hf and O isotopes based on large numbers of measurements by LA‐multiple collector (MC)‐ICP‐MS and SIMS, respectively. Precise determinations of O isotopes by isotope ratio mass spectrometry (IRMS) and Hf isotopes by solution MC‐ICP‐MS were in good agreement with the statistical mean of microbeam measurements. The mean δ 18 O value of 5.31 ± 0.10‰ (2 s ) by IRMS and the mean 176 Hf/ 177 Hf value of 0.282906 ± 0.0000010 (2 s ) by solution MC‐ICP‐MS are the best reference values for the Penglai zircons. SIMS and isotope dilution‐TIMS measurements yielded consistent 206 Pb/ 238 U ages within analytical uncertainties, and the preferred 206 Pb/ 238 U age was found to be 4.4 ± 0.1 Ma (95% confidence interval). The young age and variably high common Pb content make the Penglai zircons unsuitable as a primary U–Pb age reference material for calibration of unknown samples by microbeam analysis; however, they can be used as a secondary working reference material for quality control of U–Pb age determination for young (particularly < 10 Ma) zircon samples.